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Patent Abstract
A flexible abrasion resistant omnidirectionally reflective jewelry
piece has a central cylindrical braided rope core surrounded by
a cylindrical reflective braided sleeve comprising three or more
narrow width reflective strips that are braided at a shallow cylindrical
braid angle that reflect an incoming light beam back in the same
direction as it was emanated. The reflected light beam provides
accurate omnidirectional illumination of the person wearing the
reflective jewelry piece during dusk or nighttime hours. This reflective
jewelry piece is created by surrounding a central braided rope of
nylon or polyethylene fibers with a cylindrically braided reflective
sleeve. The braided reflective sleeve is composed of narrow width
reflective strips that comprise a woven or knitted narrow width
strip and a flexible nylon retroreflective sheet sown thereon. The
flexible retroreflective sheet is formed by thermally bonding corner
cube or microsphere retroreflectors to a flexible polymeric sheet.
Due to its braided construction, the reflective jewelry piece reflects
light omnidirectionally over a large angle of acceptance, illuminating
the person wearing the reflective jewelry piece, thereby providing
an improved measure of safety for the wearer.
Patent Claims
1. A reflective jewelry piece, comprising: a. a central cylindrical
braided rope core operable to sustain substantial tensile forces;
b. a cylindrical reflective braided sleeve comprising three or more
narrow width reflective strips that are braided at a shallow cylindrical
braid angle, said cylindrical reflective braided sleeve being operable
to surround said central cylindrical braided rope core thereby providing
omnidirectional reflectivity; c. said cylindrical reflective braided
sleeve substantially coated with a conformal transparent polymeric
abrasion resistant coating; d. said narrow width reflective strips
comprising a woven or knitted narrow width strip and a flexible
nylon retroreflective sheet sown thereon, said woven or knitted
narrow width strip having a show surface, said flexible retroreflective
nylon sheet comprising a flexible retroreflective sheet thermally
bonded onto a nylon mesh strip, said nylon mesh strip being sown
onto said show surface of said narrow width reflective strip; e.
said flexible retroreflective sheet having retroreflectors bonded
thereto with a transparent bond layer; f. said transparent polymeric
abrasion resistant coating having a refractive index lower than
that of said retroreflectors; and g. said jewelry piece having a
proximal end and a distal end, said proximal end having a female
connector thereon and said distal end having a male connector thereon,
said female connector being operable with said male connector to
attach said jewelry piece onto a person so that said jewelry provides
omnidirectional reflectivity.
2. A reflective jewelry piece as recited by claim 1, wherein said
central cylindrical braided rope core comprises braided nylon fibers.
3. A reflective jewelry piece as recited by claim 1, wherein said
central cylindrical braided rope core comprises braided polypropylene
fibers.
4. A reflective jewelry piece as recited by claim 1, wherein said
cylindrical reflective braided sleeve is braided at a braid angle
of 5 to 10 degrees.
5. A reflective jewelry piece as recited by claim 1, wherein each
of said narrow width reflective strips has a width of 0.0065 to
0.25 inches.
6. A reflective jewelry piece as recited by claim 1, wherein said
flexible retroreflective sheet is thermally bonded to said woven
or knitted narrow width strip with polyvinyl chloride.
7. A reflective jewelry piece as recited by claim 1, wherein said
flexible retroreflective sheet is thermally bonded to said woven
or knitted narrow width strip with polyvinyl acetate.
8. A reflective jewelry piece as recited by claim 1, wherein said
flexible retroreflective sheet is thermally bonded to said woven
or knitted narrow width strip with polyurethane.
9. A reflective jewelry piece as recited by claim 1, wherein said
flexible retroreflective sheet comprises a plurality of corner cube
retroreflectors.
10. A reflective jewelry piece as recited by claim 1, wherein said
flexible retroreflective sheet comprises a plurality of microsphere
retroreflectors bonded to a light-reflecting sheet.
11. A reflective jewelry piece as recited by claim 1, wherein said
retroreflectors have a refractive index in the range of 1.9 to 2.2.
12. A reflective jewelry piece as recited by claim 1, wherein said
transparent polymeric abrasion resistant coating has a refractive
index in the range of 1.3 to 1.55.
13. A reflective jewelry piece as recited by claim 1, wherein said
transparent polymeric abrasion resistant coating has a thickness
in the range of 0.002 to 0.010 inches.
14. A reflective jewelry piece as recited by claim 1, wherein said
transparent polymeric abrasion resistant coating polymer is a member
selected from the group consisting of polyurethane, silicone, polymethyl
methacralate, and polyvinyl acetate.
15. A reflective jewelry piece as recited by claim 14, wherein
said polyurethane is aliphatic polyurethane.
16. A reflective jewelry piece as recited by claim 14, wherein
said polyurethane is melt extruded.
17. A reflective jewelry piece as recited by claim 14, wherein
said polyurethane is dissolved in a solvent and sprayed on the said
cylindrical reflective braided sleeve.
18. A reflective jewelry piece as recited by claim 14, wherein
said silicone comprises a silicone composition having a viscosity
in the range of 100-275 CPS.
19. A reflective jewelry piece as recited by claim 1, wherein said
jewelry piece functions as a necklace.
20. A reflective jewelry piece as recited by claim 1, wherein said
jewelry piece functions as a bracelet.
21. A reflective jewelry piece as recited by claim 1, wherein said
jewelry piece functions as an armband.
22. A reflective jewelry piece as recited by claim 1, wherein said
jewelry piece functions as a headband.
23. A reflective jewelry piece as recited by claim 1, wherein said
jewelry piece functions as a waistband.
24. A reflective jewelry piece as recited by claim 1, wherein said
male connector is composed of a metallic material and said female
connector comprises a magnetic portion adapted to magnetically engage
with said male connector.
25. A reflective jewelry piece as recited by claim 1, wherein said
male connector comprises a magnetic member and said female connector
is composed of a metallic material so that said male and female
connectors magnetically engage with one another.
26. A reflective jewelry piece as recited by claim 1, wherein said
male connector comprises a magnetic member and said female connector
comprises a magnetic portion so that said male and female magnetically
engage with one another.
27. A reflective jewelry piece as recited by claim 1, wherein said
male connector comprises a ribbed portion and said female connector
comprises a grooved aperture adapted to receive said ribbed portion
of said male connector.
28. A reflective jewelry piece as recited by claim 1, wherein said
male connector and said female connector comprise a connection means,
said connection means selected from the group consisting of a Velcro,
hook and eye closure, snap closure, hook closure, or clasp closure.
29. A reflective jewelry piece, comprising: a. a central cylindrical
braided rope core operable to sustain substantial tensile forces;
b. a cylindrical reflective braided sleeve comprising three or more
narrow width reflective strips that are braided at a shallow cylindrical
braid angle, said cylindrical reflective braided sleeve being operable
to surround said central cylindrical braided rope core thereby providing
omnidirectional reflectivity; c. said narrow width reflective strips
comprising a woven or knitted narrow width strip and a flexible
nylon retroreflective sheet sown thereon, said woven or knitted
narrow width strip having a show surface, said flexible retroreflective
nylon sheet comprising a flexible retroreflective sheet thermally
bonded onto a nylon mesh strip, said nylon mesh strip being sown
onto said show surface of said narrow width reflective strip; d.
said flexible retroreflective sheet having retroreflectors bonded
thereto with a transparent bond layer; and e. said jewelry piece
having a proximal end and a distal end, said proximal end having
a female connector thereon and said distal end having a male connector
thereon, said female connector being operable with said male connector
to attach said jewelry piece onto a person so that said jewelry
provides omnidirectional reflectivity.
30. A process for manufacture of a reflective jewelry piece, comprising
the steps of: a. selecting a braided nylon or polypropylene cylindrical
central rope, said cylindrical central rope having a proximal end,
a distal end, and an external surface; b. attaching a female connector
to said proximal end of said central rope; c. attaching a male connector
to said distal end of said central rope, said female connector being
operable with said male connector to attach said jewelry piece onto
a person so that said jewelry provides omnidirectional reflectivity;
d. selecting a flexible polymer sheet; e. coating said flexible
polymer sheet with a plurality of retroreflectors using a transparent
binder to form a retroreflector coated flexible polymer sheet; f.
thermally bonding said retroreflector coated flexible polymer sheet
to a nylon mesh strip to form a flexible nylon retroreflective sheet;
g. sowing said flexible nylon retroreflective sheet to a narrow
width reflective strip; h. braiding at least three of said narrow
width reflective strips at a shallow cylindrical braid angle to
form an omnidirectionally reflective sleeve having a braided construction;
i. applying a transparent flexible polymeric abrasion resistant
conformal coating to substantially cover said omnidirectionally
reflective sleeve; and j. covering said external surface of said
cylindrical central rope with said omnidirectionally reflective
sleeve to provide said reflective jewelry piece with omnidirectional
reflectivity; said omnidirectionally reflective jewelry piece being
operable to sustain abrasion, substantial tensile forces, and to
accommodate twist and flexure forces due to strength and movement
afforded by said braided construction of said omnidirectionally
reflective sleeve.
Patent Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application is a continuation-in-part of U.S. application
Ser. No. 11/185,059, filed Jul. 20, 2005, which, in turn, is a continuation-in-part
of U.S. application Ser. No. 11/067,442, filed Feb. 25, 2005, which,
in turn, is a continuation-in-part of U.S. application Ser. No.
10/935,687, filed Sep. 8, 2004, now U.S. Pat. No. 6,925,965, which,
in turn, claims the benefit of Application No. 60/591,936, filed
Jul. 28, 2004.
BACKGROUND OF THE INVENTION
[0002] 1. Field of the Invention
[0003] The present invention relates to reflective jewelry; and
more particularly, to abrasion resistant omnidirectionally reflective
jewelry especially suited for use during dusk or nighttime hours
to enhance safety of a person while walking, hiking, jogging, bicycling,
or the like, in the vicinity of land vehicles and / or other light
emitting sources.
[0004] 2. Description of the Prior Art
[0005] Walking, hiking, jogging, bicycling, engaging in sport activities,
or the like, during dusk or nighttime hours can be hazardous in
neighborhoods where automobiles are encountered. Illuminating characteristics
of the automobile headlamps, generally afford an illumination range
of approximately 25 to 50 feet. This illumination range can be significantly
reduced by mist or fog, or bends in the road. Despite improvements
to vehicle headlights, pedestrians are oftentimes not recognized
by automobile drivers until the distance between the automobile
and the pedestrian is small. The same principle holds true for persons
in marine craft such as dinghy's, sunfish and the like, which may
be navigating on rivers, lakes, harbors, inland waterways and other
boating areas.
[0006] Use of high intensity illumination is not always possible
since it is difficult and cumbersome for an individual participating
in such activities to carry an illuminating light source, such as
a flashlight. Even still, carrying an illuminating light source
during sporting activities is oftentimes ineffective due to the
limited illumination distances realized by hand-held illumination
sources. In such situations, poor illumination can present a high
level of danger. Higher intensity, bright illumination sources do
not solve this hazard, since these high intensity light sources
tend to be relatively bulky and heavy, and therefore are far less
convenient to carry while walking, jogging, or participating in
sport activities during dusk or nighttime hours.
[0007] Several approaches devised by prior art workers attempt
to provide solutions for hazardous conditions resulting from common
outdoor activities, such as walking, hiking, jogging, bicycling,
engaging in sport activities, or the like. Many of these approaches
revolve around pedestrians walking their pets; such approaches have
been utilized to provide safer conditions for the pets. These approaches
include 1) use of pet collars that are illuminated or reflective;
2) use of leashes which are illuminated or reflective; or 3) a combination
of both features. None of these solutions suggest indicating the
whereabouts of a pedestrian or person engaging in a sporting activity
via omnidirectional reflection.
[0008] Various types of illumination devices are known in the art.
Many of these illumination devices involve use of bulbs or other
powered sources associated with dog collars. These power-illuminated
leashes require batteries, light bulbs or other lighting elements,
which are not needed for reflective illumination. Accordingly, a
detailed discussion thereof is not required.
[0009] U.S. Pat. No. 4,173,201 to Chao, et al. discloses an illuminated
collar for pets and the like. U.S. Pat. No. 4,513,692 to Kuhnsman,
et al. discloses an illuminated pet leash comprising a non-opaque
tube that contains one or more bundles of optical fibers. U.S. Pat.
No. 4,895,110 to Lo Cascio discloses a pet collar that includes
a light source and a power source attached to a strap. U.S. Pat.
No. 4,887,552 to Hayden discloses an electrically lighted pet leash
that is composed of a transparent, flexible tube containing a string
of small electric light bulbs mounted in parallel between two insulated
wires. U.S. Pat. No. 5,046,456 to Heyman, et al. discloses an illuminated
pet collar in which multiple lights are mounted within a flexible,
light-permeable tube that extends about the perimeter of the collar.
A housing mounted on one end of the tube contains a circuit and
a battery for operating the lights. U.S. Pat. No. 5,140,946 to Pennock,
et al. discloses an illuminated pet collar with miniature lights
powered by a battery encased within a flexible, pliable, transparent
plastic display tube, which are parallel-wired within the display
tube. U.S. Pat. No. 5,370,082, to Wade discloses an animal collar
that includes illuminating devices, such as light emitting diodes,
liquid quartz strips or electric lamps powered by a plurality of
solar cells. U.S. Pat. No. 5,429,075 to Passarella, et al. discloses
a pet leash and flashlight combination. U.S. Pat. No. 5,523,927
to Gokey discloses an illuminated animal collar light emitting diode
placed on the outer exterior of a collar powered by a battery. U.S.
Pat. No. 5,535,106, issued to Tangen, discloses a lighted animal
collar that includes a plurality of separate light emitting assemblies,
or housings, at spaced intervals along the collar. U.S. Pat. No.
5,558,044 to Nasser, Jr. et al. discloses an illuminating leash
handle with a flashlight. U.S. Pat. No. 5,630,382 to Barbera, et
al. discloses an illuminated pet harness having straps with internal
cavities that contain fiber optic cores illuminated by a light bulb.
U.S. Pat. No. 5,762,029 to DuBois, et al. discloses a combined retractable
leash and flashlight. U.S. Pat. No. 5,850,807 to Keeler discloses
an illuminated pet leash, wherein illumination is remotely activated
by a pet owner to locate the leash. U.S. Pat. No. 5,967,095 to Greves
discloses an electroluminescence-illuminated pet flat leash strap.
U.S. Pat. No. 6,170,968 to Caswell discloses a motion activated
rotatable illuminator. U.S. Pat. No. 6,289,849 to Macedo, et al.
discloses a device for removably attaching a flashlight to a retractable
dog leash. U.S. Pat. No. 6,557,498 to Smierciak, et al. discloses
a night safety pet illumination marker, with a pet collar having
a series of light emitting diodes mounted around the perimeter of
the collar and powered by battery power.
[0010] Various types of devices involving reflective illumination
are known in the art; many of these devices involve reflective dog
collars. Representative dog collars of this variety are discussed
below.
[0011] U.S. Pat. No. 3,871,336 to Bergman discloses a reflective
dog collar which is not illuminated; but which utilizes a highly
reflective material having the form of different color dots encapsulated
in plastic. This illuminates only portions of the flat planar pet
collar. Moreover, the reflective dog collar disclosed by the '336
patent cannot feasibly be utilized as reflective jewelry to be worn
by a person.
[0012] U.S. Pat. No. 3,999,521 to Puiello discloses a reflective
safety harness for quadruped animals. The harness includes a pair
of identical sheet elements with a light reflective surface mounted
on opposite sides of the animal. At the corners of the sheet are
fastened straps, which circumscribe the animal's body at the front
and rear of the harness. Extending from the front strap, at the
top point thereof, midway between the two elements, is a loop through
which the dog's regular collar is passed. The arrangement assures
immovable attachment of the harness on the dog's body. The disclosure
by the '521 patent of a reflective sheet positioned on both sides
of the animal does not suggest a jewelry piece that is worn by a
person and reflects incident light.
[0013] U.S. Pat. No. 4,167,156 to Kupperman, et al. discloses a
reflective animal leather leash. The elongated leather animal leash
includes a sewn a transparent polyvinyl chloride strip with a light
reflective prism design on one surface. The light reflective prism
is bonded by dielectric heat sealing or sonic welding to an opaque
polyvinyl chloride strip sewn to the leather strip, resulting in
a leash having a light reflective surface. Since the strip has a
reflective surface on only one side of the leash, it does not reflect
light in every direction. The flat leather leash is not easily twistable
and is not readily bent without separating the transparent and opaque
polyvinyl chloride layers. Moreover, the leather leash cannot feasibly
be utilized as reflective jewelry to be worn by a person.
[0014] U.S. Pat. No. 4,384,548 to Cohn discloses a safety device
for animals. A pet collar uses "retro-reflective" threads
with glass reflective elements in a flexible webbing to form a pet
leash. The threads are said to reflect incident light directly back
toward the source. Disposition of reflective threads in the webbing
forming the collar is sparce. As a result, the quantum of incident
light reflected is small; and an insignificant quantum of incident
light is reflected back to the source.
[0015] U.S. Pat. No. 4,407,233 to Bozzaco discloses a safety collar
for pets. The collar has highly reflective flexible elements with
a length large enough to extend beyond the outer surface of the
pet's hair. It uses flexible elements with Scotchlite reflecting
strips attached to a collar. A reflective jewelry piece is not disclosed,
and the flexible elements do not reflect light in every direction.
[0016] U.S. Pat. No. 5,243,457 to Spencer discloses a material
with enhanced visibility characteristics. This flexible visibility
enhancing material combines the advantages of a light reflective
component and a luminescent component. The material includes a first
layer of prismatic light reflective plastic material having an underlying
surface formed with a plurality of minute prism-like formations
projecting there from at regular spaced intervals, and an overlying
substantially smooth light transmissive surface. Bonded, i.e. by
heat-sealing, to the first layer is a second layer of plastic luminescent
material. The second layer is contiguously and integrally attached
to the underlying surface of the prism-like formations and generally
coextensive therewith. The visibility enhancing material simultaneously
radiates luminescent light from the second layer through the underlying
surface of prism-like formations and through the smooth light transmissive
surface and reflects light from the prism-like formations through
the smooth light transmissive surface. In one embodiment, a leash
for controlling and restraining a pet animal includes a flexible
elongate member comprised of the visibility enhanced material. In
another embodiment, the second layer is replaced with a layer of
luminescent material, which can be selectively energized to become
luminous. Since the transparent reflective material is a molded
plastic of prismatic construction it is rigid and is not flexible
and does not form a reflective jewelry piece that is capable of
being twisted and bent, or worn by a person. Further any twisting
and bending action separates the reflective element from the luminescent
element.
[0017] U.S. Pat. No. 5,237,448 to Spencer, et al. discloses a visibility
enhancing material. The flexible visibility enhancing material combines
the advantages of a light reflective component and a luminescent
component. The material includes a first layer of prismatic light
reflective plastic material having an underlying surface formed
with a plurality of minute prism-like formations projecting therefrom
at regular spaced intervals, and an overlying substantially smooth
light transmissive surface. A second layer of plastic luminescent
material is contiguously and integrally attached to the underlying
surface of the prism-like formations and generally coextensive therewith.
The visibility enhancing material simultaneously radiates luminescent
light from the second layer through the underlying surface of the
prism-like formations and through the smooth light transmissive
surface, and reflects light from the prism-like formations through
the smooth light transmissive surface. In one embodiment, a leash
for controlling and restraining a pet animal includes a flexible
elongate member comprised of the visibility enhanced material. Since
the transparent reflective material is a molded plastic of prismatic
construction, it is rigid and is not flexible and does not form
a reflective jewelry piece that is capable of being twisted and
bent, or worn by a person. Furthermore, any twisting and bending
action will result in separation of the reflective element from
the luminescent element.
[0018] U.S. Pat. No. 6,070,556 to Edwards discloses an illuminating
dog safety system. This illuminating dog safety system is designed
for allowing an animal to be more visible at night. The device includes
a collar that is worn around a neck of an animal. The collar has
a reflective strip extending a majority of its length. A harness
is provided that is adapted to be worn around a torso of the animal.
The harness is comprised of an upper strap member, a lower strap
member, and a longitudinal extension there between. The upper strap
member, the lower strap member, and the longitudinal extension each
have a reflective strip extending a majority of a length thereof.
A leash is provided that is adapted for securement to the collar.
The leash has a reflective strip extending a majority of its length.
All these strip elements are made from flat elements, as shown in
FIG. 3 of the patent disclosure. Twisting the elements does not
provide the reflectivity needed for adequate visibility at night.
[0019] Numerous patents disclose reflective materials. Some of
these patents disclose reflective elements having corner cube shapes
embedded in a rigid or flexible polymeric strips and monolayers
of spherical beads, i.e. primarily glass beads bonded to a reflective
sheet.
[0020] U.S. Pat. No. 3,176,584 to DeVries, et al. discloses that
a reinforcing layer may be incorporated into an embedded lens retroreflective
sheeting. The reinforcing layer may be of a similar composition
as the binder in which the microspheres are embedded. The layer
may be applied to the back side of the secularly reflective layer
via spraying, i.e., by a solvent-coating technique. Examples of
the reinforcing layer materials disclosed include methyl methacrylate,
flexible epoxy resins, chloro-sulfonated polyethylene, polystyrene,
polypropylene, polycarbonate resin, ethyl cellulose, and cellulose
acetate-butyrate. The reflective layer is typically very thin and
fragile, i.e. in the order of 0.06 microns thick, and must be disposed
in special relationship to the microspheres in order for the sheeting
to provide useful retro-reflection.
[0021] U.S. Pat. No. 3,190,178 to McKenzie discloses a reflex reflective
sheeting. It uses a monolayer of microspheres embedded in a polymer
to reflect the incoming light beam in the same direction as the
incident beam. Since the sheet is formed by melting of the polymeric
binder, it is rigid and therefore unsuitable for reflective jewelry.
[0022] U.S. Pat. No. 4,025,159 to McGrath discloses cellular retroreflective
sheeting. The cellular retroreflective sheeting comprises a base
layer of retroreflective elements and a transparent cover film supported
in spaced relation away from the base layer by a network of narrow
intersecting bonds. These bonds form hermetically sealed cells within
which retroreflective elements are isolated from retroreflective
elements of different cells. The resultant sheeting achieves greater
durability through use of bonds that are cured in situ after they
have been thermoformed into sealing contact between the cover film
and base layer. The base material is coated with the binder, subjected
to heat and pressure to displace the binder around the embedded
microsphers or corner cubes forming the bonded network. Retroreflective
articles so constructed may be rigid and inflexible.
[0023] U.S. Pat. No. 4,576,850 to Martens, and U.S. Pat. Nos. 4,582,885,
4,668,558 to Barber disclose a shaped plastic articles having replicated
microstructure surfaces. This shaped plastic article is made by
crosslinked polymer with hard and soft segments having a microstructure-bearing
surface that is replicated, with a castable fluid, and radiation
hardened. Articles formed by this process exhibit, a retro-reflective
cube-corner sheeting, Fresnel lens or video disc. All these formed
articles are rigid and therefore unsuitable for use in reflective
jewelry. Moreover, these articles also exhibit low tear strength.
[0024] U.S. Pat. No. 4,763,985 to Bingham discloses a launderable
retroreflective applique that comprises a layer of transparent microspheres,
a specular reflective layer optically connected to each microsphere,
and a binder layer into which the microspheres are partially embedded.
Resins disclosed as being suitable for use as binder layers include
polyurethane, polyesters, polyvinyl acetate, polyvinyl chloride,
acrylics, or combinations thereof. The specular reflective layers
are composed of two succeeding layers of dielectric material. The
layers have varying refractive indices and are composed of a variety
of binary metal compounds including oxides, sulfides, and fluorides.
[0025] U.S. Pat. No. 4,815,818 to Thomas discloses three-dimensional
flexible reflectors. The reflector is provided with elastomeric
resilient member with a plurality of embedded retro-reflective glass
beads. A portion of the outer surface of the elastomeric material
is removed to expose the glass beads. The exterior surface of the
glass beads at the outer surface is exposed and is subject to abrasion.
[0026] U.S. Pat. No. 4,950,525 to Bailey discloses elastomeric
retroreflective sheeting. The elastomeric retroreflective sheeting
has a monolayer of non-stretchable microspheres. These microspheres
are embedded in a sheet with a spacing layer of transparent elestomeric
material underlying the back surface of the microspheres. A cover
layer of transparent elastomeric material covers the front surface
of the microspheres. A specularly reflective layer is disposed on
the back surface of the spacing layer. The cover layer comprises
a clear thermoplastic elastomeric aliphatic polyurethane.
[0027] U.S. Pat. No. 4,957,335 to Kuney discloses microsphere-based
retro-reflective articles having high retroreflective brightness
at narrow divergence or observation angles, i.e. up to 0.5 degrees.
The article is made by selection of microspheres having defined
combinations of average diameter and average refractive index. This
patent teaches (column 4, lines 18-23) that variation in the size
of the microspheres will increase the observation angle or divergence
angle of the resultant retro-reflective article.
[0028] U.S. Pat. No. 5,066,098 to Kult, et al. discloses cellular
encapsulated-lens high whiteness retroreflective sheeting with a
flexible cover sheet. This cellular, encapsulated-lens retroreflective
sheeting comprises a base sheet of a monolayer of retroreflective
elements that is partially embedded in a binder layer which typically
is white. A cover sheet is disposed in spaced relation from the
layer of retroreflective elements. A network of narrow intersecting
bonds, or seal legs, that extend between the cover sheet and the
base sheet with binder material are thermoformed at the point of
contact between the base sheet and cover sheet. Such a rigid, reflective
sheet is unsuitable for pet leashes, which require structures that
can twist and flex.
[0029] U.S. Pat. No. 5,117,304 to Huang, et al. discloses a retroreflective
article. The retroreflective article has corner cubes and is flexible,
and can be applied over irregular surfaces by using an optically
clear, aliphatic polyurethane polymer. The aliphatic polymer has
a plurality of hard chain segments having the formula --C(O)N(H)--C.sub.6H.sub.10--N(H)C(O)--.
[0030] U.S. Pat. No. 5,200,262 to Li discloses a launderable retroreflective
applique. The applique employs a reflector that comprises elemental
aluminum or elemental silver on the backside of the microspheres.
The applique comprises a monolayer of metal-coated microspheres
partially embedded in and partially protruding from a binder layer.
The binder layer comprises a flexible polymer having hydrogen functionalities
and one or more isocyanate-functional silane coupling agents. The
disclosed flexible polymers that possess hydrogen functionalities
are crosslinked, flexible urethane-based polymers, such as isocyanate-cured
polymers or one or two component polyurethanes and polyols.
[0031] U.S. Pat. No. 5,283,101 to Li discloses a launderable retroreflective
applique comprising a binder layer formed from an electron-beam
curable polymer and typically one or more crosslinkers and silane
coupling agents. Electron-beam curable polymers include chlorosulfonated
polyethylenes, ethylene copolymers comprising at least about 70
weight percent of polyethylene, such as ethylene/vinyl acetate,
ethylene/acrylate, and ethylene/acrylic acid, and poly(ethylene-co-propylene-co-diene)
polymers. Glass microspheres are embedded in the cured binder layer,
and a specular reflective metal layer is disposed on the embedded
portions thereof. When the applique is inverted, light comes through
the binder layer.
[0032] U.S. Pat. No. 5,777,790 to Nakajima discloses a microsphere-based
retroreflective article. The retroreflective article comprises a
monolayer of microspheres partially embedded in and protruding from
a binder layer and specular reflector underlying the microspheres.
The monolayer of microspheres comprises a mixture of a first class
of microspheres having a first refractive index and a second class
of microspheres having a second refractive index. The second refractive
index is higher than the first refractive index. As a result, the
sheeting exhibits superior observation angle angularity.
[0033] U.S. Pat. No. 5,882,796 to Wilson, et al. discloses bonded
structured retroreflective sheeting. The structured retroreflective
sheeting includes an array of corner cube structured retroreflective
elements, a thermoplastic sealing film located proximate the structured
elements, and bonding agent between the sealing film and the structured
retroreflective elements. The bonding agent bonds the sealing film
to the structured retroreflective film. This bonded structure is
rigid and is unlikely to survive the flexing and twisting movements
of a reflective jewelry piece.
[0034] U.S. Pat. No. 5,926,314 to Smith, et al. discloses a retroreflective
cube corner article having scalene base triangles. The cube corner
retroreflective article exhibits a wide range of retroreflective
entrance angularity in at least one plane, and preferably in two
or more planes. The structured surface has an array of cube corner
elements formed by three intersecting sets of substantially parallel
grooves. Each cube corner element includes a base triangle bonded
by one groove from each of the three intersecting groove sets, the
base triangle being scalene. The corner cube reflector is rigid
and cannot be used for producing reflective jewelry.
[0035] U.S. Pat. No. 5,962,108 to Nestegard, et al. discloses a
retroreflective polymer coated flexible fabric material and method
of manufacture. The retroreflective polymeric coated flexible fabric
material has a retroreflective layer and a polymeric compatibilizing
layer welded to a polymeric coated outer surface of a flexible fabric
material. The compatibilizing layer provides an intermediate layer
between the retroreflective layer and the flexible fabric material,
creating suitable bond strength between dissimilar polymers. Flexible
fabric materials are polyester, nylon or cotton. The fabric is coated
with highly plasticized polyvinyl chloride (PVC) or ethylene acrylic
acid copolymer (EAA). These polymers are flexible, durable, and
resistant to abrasion. The retroreflective prismatic elements layer
includes: acrylic polymers, such as poly(methylmethacrylate); polycarbonates;
cellulosics; polyesters such as poly(butyleneterephthalate); poly(ethyleneterephthalate);
fluoropolymers; polyamides; polyetherketones; poly(etherimide);
polyolefins; poly(styrene); poly(styrene) co-polymers; polysulfone;
urethanes, including aliphatic and aromatic polyurethanes; and mixtures
of the above polymers such as a poly(ester) and poly(carbonate)
blend, and a fluoropolymer and acrylic polymer blend. The compatibilizing
layer that is suitable for bonding between a retroreflective layer
and a flexible fabric material include: polyurethane, ethylene methyl
acrylate copolymer, ethylene N-butyl acrylate copolymer, ethylene
ethyl acrylate copolymer, ethylene vinyl acetate copolymer, polymerically
plasticized PVC, and polyurethane primed ethylene acrylic acid copolymer.
Such a reflective fabric does not suggest the shape, construction
or function of a reflective jewelry piece.
[0036] U.S. Pat. No. 5,910,858 to Frey discloses retroreflective
sheeting with a coated back surface. The retroreflective sheet has
a plurality of indentations on the back surface to reflect the light,
and a transparent front surface to encapsulate and protect the light
reflecting indentations. This reflective sheet is rigid and is unsuitable
for use in reflective jewelry.
[0037] U.S. Pat. No. 6,159,537 to Crandall discloses a method of
making a retroreflective article that has a binder layer containing
an epoxy resin and silicone crosslinked polymer. A pre-binder composition
comprises about 5 to about 40 parts of an epoxy resin. About 60
to about 95 parts of an alkoxysilane terminated polymer is applied
to a retroreflective layer and then cured to form a binder layer
that is adhered to the retroreflective layer and an article of clothing.
The binder composition does not cover the exterior surface of the
reflective layer and does not provide abrasion resistance.
[0038] U.S. Pat. No. 6,677,028 to Lasch, et al. discloses retroreflective
articles having multilayer films and methods of manufacturing same.
These retroreflective articles have multilayer films and are useful
for commercial graphics and retroreflective products, such as roll-up
signs for highway transportation safety. The articles comprise multilayer
films having at least one layer of polyurethane and a core layer
of a copolymer of alkylene and a bond layer of non-acidic, polar
co-monomer including, ethylene copolymer, vinyl acetate, acrylate,
EVA, acid-modified EVA, anhydride-modified EVA, acid-acrylate-modified
EVA, anhydride-acrylate-modified EVA, EEA, EMA, AEA, EVACO, EBACO,
and EnBA. The glass retroreflective beads comprise an air-exposed
portion or have an overlay polyurethane or EAA cover film. When
retroreflective glass beads are exposed to air, they are subject
to wear.
[0039] Notwithstanding the efforts of prior art workers to construct
safety wear reflective jewelry devices that are illuminated by incident
light, there remains a need in the art for a flexible abrasion resistant
jewelry piece that omnidirectionally reflects a significant quantum
of incoming light back to its source. Numerous methods for producing
retroreflectors have been disclosed. A flexible reflective jewelry
piece having flexible, omnidirectional abrasion resistant construction
has long been needed in the art. Also needed is a jewelry piece
capable of maintaining high reflectivity when subjected to surface
abrasion from frictional forces created by contact of the jewelry
with a person's skin, clothing, or perspiration from physical exertion.
SUMMARY OF THE INVENTION
[0040] The present invention provides a reflective jewelry piece
that is abrasion resistant and omnidirectionally reflective. Omnidirectional
reflectivity is provided by the incorporation of retroreflective
corner cube reflectors or microsphere reflective elements thermally
bonded onto a nylon mesh strip to form a flexible nylon retroreflective
sheet, which is in turn sown onto a narrow width reflective strip.
With this structure, the jewelry reflects a significant quantum
of the incident light from a car head light or other light emitting
element back to the source. The abrasion resistance property of
the jewelry is provided by a transparent coating. One such coating
comprises a polymer that is transparent, flexible and has a refractive
index significantly smaller than that of the retroreflective elements
used.
[0041] Abrasion resistance and omnidirectional reflectivity is
achieved by: a) creating a flexible retroreflective sheet comprising
a plurality of corner cube reflectors bonded via a transparent bond
to a flexible polymeric sheet, or several microspheres bonded via
a transparent bond to a reflectorized flexible polymeric sheet;
b) producing a narrow width strip composed of nylon or polypropylene
fibers by knitting, weaving or braiding, to achieve a strip width
in the range of 0.0065 inch to 0.25 inch, depending upon the size
of the central cylindrical rope core; c) thermally bonding a flexible
retroreflective sheet onto a nylon mesh strip to form a flexible
nylon retroreflective sheet which is in turn sown onto a show surface
of the narrow width strip, thereby forming a narrow width reflective
strip; d) cylindrically braiding, at a shallow braid angle, three
or more narrow width reflective strips to surround and cover the
external surface of a central cylindrical core made from braided
nylon or polypropylene fibers; e) forming a cylindrical retroreflective
braided sleeve integrally surrounding a central cylindrical core
to thereby create a jewelry piece having an external retroreflector
surface; and f) coating the external surface of the cylindrical
retroreflective braided sleeve with a transparent, flexible abrasion
resistant coating having a refractive index significantly less than
that of the retroreflective elements. The thickness of the transparent
abrasion resistant coating is in the range of 0.002 to 0.010 inches.
[0042] The jewelry piece comprises a proximal end and a distal
end. The proximal end includes a female connector thereon and the
distal end includes a male connector thereon. The female connector
is operable with the male connector to attach the jewelry piece
onto a person so that the jewelry provides omnidirectional reflectivity.
The entire length of the jewelry piece reflects the incident light
from a car's headlights or other light source back to the source
illuminating the position of the person wearing the jewelry piece.
[0043] Optionally, the reflective jewelry piece's male connector
is composed of a metallic material and the female connector is comprised
of a magnetic portion adapted to magnetically engage with the male
connector. Alternatively, the male connector is comprised a magnetic
member and the female connector is composed of a metallic material
so that the male and female connectors magnetically engage with
one another. The male connector may comprise a magnetic member and
the female connector may comprise a magnetic portion so that the
male and female magnetically engage with one another. In another
embodiment, the male connector comprises a ribbed portion and the
female connector comprises a grooved aperture adapted to receive
the ribbed portion of the male connector. Alternatively, the male
connector and the female connector comprise a connection means,
wherein the connection means is selected from the group consisting
of a Velcro, hook and eye closure, snap closure, hook closure, or
clasp closure. The transparent abrasion resistant coating may be
applied to the entire length of the jewelry piece between the proximal
and distal ends.
[0044] The reflective jewelry piece may function as a necklace.
Alternatively, the reflective jewelry piece functions as a bracelet.
The reflective jewelry piece may function as an armband, headband,
or a waistband.
[0045] The cylindrical character of the flexible cylindrical braided
sleeve reflects a significant quantum of incident light back to
the source effectively since some portion of the braided sleeve
is always at angles close to normality and most of the braided cylindrical
sleeve falls within the reflecting angular range of the retroreflectors.
The shallow braiding angle of the cylindrical braid sleeve lays
the thermally bonded narrow width strips at a shallow angle with
respect to the length of the cylindrical central core. As a result
the can be readily flexed or twisted due to the relative movement
provided within the cylindrical braid sleeve structure. The flexibility
of the transparent abrasion resistant coating provides for flexing
and twisting movement of the abrasion resistant reflective jewelry
without coating separation or delamination.
[0046] The external surface of the cylindrical retroreflective
braided sleeve is coated with a transparent, flexible abrasion resistant
polymeric coating. The coating has a refractive index significantly
lesser than that of retroreflective elements. Typically the retroreflective
elements have a refractive index of 1.9 to 2.2 and the flexible
transparent abrasion resistant polymeric coating has a refractive
index of 1.3 to 1.55. A 0.002 to 0.010 inch layer of transparent
flexible abrasion resistant polymeric coating does not affect the
path of normally incident incoming light beam. With such a coating
alteration of the path of inclined incident light beam is minimal.
Similarly, the reflected light beam path is not severely affected.
The internal reflection property of the retroreflective elements
is not deteriorated since the abrasion resistant coating has significantly
lower refractive index, as compared to that of the retroreflective
elements.
[0047] The jewelry comprises a cylindrical reflective braided sleeve
having three or more narrow width reflective strips that braided
at a shallow cylindrical braid angle, said cylindrical reflective
braided sleeve being operable to surround the central cylindrical
braided rope core thereby providing omnidirectional reflectivity.
Each narrow width reflective strip has a flexible nylon retroreflective
sheet sown to their show surface. The flexible nylon retroreflective
sheet is formed by thermally bonding a retroreflector coated flexible
polymer sheet to a nylon mesh strip.
[0048] In another embodiment, the reflective jewelry piece, comprises:
(i) a central cylindrical braided rope core operable to sustain
substantial tensile forces; (ii) a cylindrical reflective braided
sleeve comprising three or more narrow width reflective strips that
are braided at a shallow cylindrical braid angle, said cylindrical
reflective braided sleeve being operable to surround said central
cylindrical braided rope core thereby providing omnidirectional
reflectivity; (iii) said narrow width reflective strips comprising
a woven or knitted narrow width strip and a flexible retroreflective
sheet, said woven or knitted narrow width strip having a show surface,
and said flexible retroreflective sheet being thermally bonded onto
said show surface thereof; (iv) said flexible retroreflective sheet
having retroreflectors bonded thereto with a transparent bond layer;
and (v) said jewelry piece having a proximal end and a distal end,
said proximal end having a female connector thereon and said distal
end having a male connector thereon, said female connector being
operable with said male connector to attach said jewelry piece onto
a person so that said jewelry provides omnidirectional reflectivity.
BRIEF DESCRIPTION OF THE DRAWING
[0049] The invention will be more fully understood and further
advantages will become apparent when reference is had to the following
detailed description of the preferred embodiments of the invention
and the accompanying drawings, in which:
[0050] FIG. 1a is a photograph of the reflective jewelry piece
showing the reflective cylindrical braided sleeve of narrow width
strips covering a central core, and further showing the male and
female connectors located on the distal and proximal ends, respectively,
taken with camera flash light showing reflective portions as bright
regions;
[0051] FIG. 1b is a photograph of the reflective jewelry piece
showing the reflective cylindrical braided sleeve of narrow width
strips covering a central core, and further showing the male and
female connectors located on the distal and proximal ends, respectively,
taken without camera flash light showing reflective portions as
dark regions; and
[0052] FIG. 2 is a photograph of the reflective jewelry piece illustrating
the details of a transparent abrasion resistant polymeric conformal
coating substantially covering the reflective cylindrical braided
sleeve of narrow width strips surrounding the central core;
[0053] FIG. 3 is a photograph of the proximal end of the reflective
jewelry piece as attached to the reflective cylindrical braided
sleeve of narrow width strips.
DETAILED DESCRIPTION OF THE INVENTION
[0054] The present invention provides an abrasion resistant reflective
jewelry piece that is flexible, twistable and omnidirectionally
reflective. It has an integral female connector attached to the
proximal end of the jewelry, and an integral male connector attached
to the distal end of the jewelry, which operate together to attach
the jewelry piece to a person's body to provide omnidirectional
reflectivity. The jewelry piece forms an omnidirectional reflective
necklace, bracelet, headband, armband, waistband, or the like, that
reflects incident light back to its source, thereby clearly defining
the whereabouts of the jewelry piece. This increases the margin
of safety in dusk or night time environments when a car headlight
can illuminate the wearer or person, reducing the possibility of
accidents. Since the omnidirectionally reflecting jewelry reflects
light over a broad range, due to its reflective cylindrical sleeve
arrangement, the headlight can be at a significant angle and could
still be reflected back.
[0055] The abrasion resistant omnidirectional jewelry is constructed
by building a cylindrically reflective sleeve from narrow width
strips of nylon or polypropylene. Reflectivity is achieved by first
selecting a flexible polymer sheet and coating the flexible polymer
sheet with a plurality of retroreflectors using a transparent binder
to form a retroreflector coated flexible polymer sheet. The retroreflector
coated flexible polymer sheet is then thermally bonded to a nylon
mesh strip to form a flexible nylon retroreflective sheet. The flexible
nylon retroreflective sheet is then sown onto a show surface of
a narrow width reflective strip. At least three of these narrow
width reflective strips are braided at a shallow cylindrical braid
angle to form an omnidirectionally reflective sleeve having a braided
construction. A female connector is then attached (fixedly) to the
proximal end of the central rope, while a male connector is attached
to the distal end of the central rope. The female connector is operable
with the male connector to attach the jewelry piece onto a person
so that the jewelry provides omnidirectional reflectivity.
[0056] The retroreflecting elements may be corner cubes, in which
case the polymeric flexible sheet can be non-reflective. Alternatively,
the retroreflecting elements may be microspheres. If microspheres
are used as retroreflective elements, the polymeric flexible sheet
needs to be reflective and is typically metallized with aluminum
or silver. In either case, the retroreflective elements are bonded
to the flexible sheet using a transparent binder.
[0057] The flexible sheet with retroreflective elements is available
from 3M Corporation. The trade name for this product is SCOTCHLITE
and the flexible polymer is typically PVC and the product is available
in a variety of sizes. This flexible reflectorized sheet is thermally
bonded to a nylon mesh strip, woven or knitted to form a flexible
nylon retroreflective sheet. The nylon mesh strip may have a width
of 0.0165 cm to 0.635 cm (0.0065 inches to 0.25 inches) and is thermally
bonded to a SCOTCHLITE strip having a width slightly less than the
width of the nylon mesh strip. The SCOTCHLITE strip is bonded the
entire length of the nylon mesh strip, and is bonded centrally on
the nylon mesh strip, so that there are equal side portions of the
nylon mesh strip on both sides of the SCOTCHLITE strip. The side
portions are then sown to a narrow width strip. The thermal bonding
binder may be selected from a number of polymeric binders including,
but not limited to, polyvinyl chloride, polyethylene, polyurethane,
polyvinyl acetate or acrylates.
[0058] The flexible nylon retroreflective sheet is highly flexible
and can be cylindrically braided visa vie through the braiding of
the narrow width strip to which it is attached via sown to the surface
thereof. At least three of these narrow width reflective strips
are braided at a shallow cylindrical braid angle to form an omnidirectionally
reflective sleeve having a braided construction surrounding a central
rope core of the jewelry, which substantially sustains any pulling
tensile forces which may result through wearing of the jewelry piece.
[0059] The abrasion resistant omnidirectional jewelry piece is
constructed by building a cylindrically reflective sleeve from the
narrow width strips of nylon or polypropylene having the flexible
nylon retroreflective sheets sown thereto. The cylindrical braiding
employs three or more narrow width strips. The cylindrical braiding
is accomplished with a small angle between narrow width strips and
the longitudinal direction of the central core rope. A female connector
is then attached (fixedly) to the proximal end of the central rope,
while a male connector is attached to the distal end of the central
rope. The female connector is operable with the male connector to
attach the jewelry piece onto a person so that the jewelry provides
omnidirectional reflectivity. The cylindrical braiding is accomplished
to cover the entire length of the jewelry piece (excluding the male
and female connectors). The ends of the braid are terminated by
permanent bonding.
[0060] The jewelry piece comprises a proximal end and a distal
end. The proximal end includes a female connector thereon and the
distal end includes a male connector thereon. The female connector
is operable with the male connector to attach the jewelry piece
onto a person so that the jewelry provides omnidirectional reflectivity.
The entire length of the jewelry piece reflects the incident light
from a car's headlights back to the source illuminating the position
of the person wearing the jewelry piece.
[0061] The transparent abrasion resistant coating may be applied
to the entire length of the jewelry piece between the proximal and
distal ends.
[0062] The reflective jewelry piece may function as a necklace.
Alternatively, the reflective jewelry piece functions as a bracelet.
The bracelet may be of the form of a bracelet worn on the wrist,
or a bracelet worn on the ankle. The reflective jewelry piece may
function as an armband, headband, or a waistband. The abrasion resistant
coating helps to mitigate damage to the reflective sleeve as the
wearer perspires on the jewelry piece, such as when the wearer is
participating in highly athletic sporting activities.
[0063] A transparent abrasion resistant coating is applied to the
outer surface of the cylindrically reflective braided sleeve of
the jewelry and is applied as a substantially conformal coating.
The reflective strips have retroreflective elements embedded in
the strips having a corner cube prismatic or microsphere geometry.
These transparent retroreflective elements are made from high refractive
index transparent materials such as barium oxide-titanium oxide
containing glasses. They exhibit a refractive index in the range
of 1.9 to 2.2. The transparent abrasion resistant polymeric coating
is selected to have a refractive index, which is significantly less
than that of the retrorefractive elements. As a result, the incident
and reflected light path is not significantly altered even when
the incident beam is inclined to the reflective strips. The internal
reflection process within the retroreflective elements is not deteriorated
by the transparent abrasion resistant coating. The polymers suitable
for use with the transparent abrasion resistant coating have a refractive
index in the range of 1.3 to 1.55.
[0064] In addition to this refractive index requirement, the transparent
abrasion resistant coating must exhibit excellent mechanical properties,
including tensile strength and elongation, in order to provide the
required abrasion resistance. The polymer coating must also exhibit
superior bond properties to the retroreflective elements and the
underlying polymeric sheet of the reflective strip. If the bond
properties are poor, the transparent abrasion resistant coating
may delaminate when the jewelry piece is subjected to abrasion or
flexing and twisting movement. The transparent abrasion resistant
coating must have low elastic modulus so that it remains flexible
when the jewelry is twisted. A high modulus transparent abrasion
resistant coating is not desired since it applies significant stresses
at the coating--reflective tape interface resulting in deterioration
or fracture of the retroreflective elements.
[0065] A number of polymer systems meet these requirements. These
polymers may be applied by dipping the cylindrically braided jewelry
piece into a polymeric melt or by spraying a polymer composition
dissolved in a suitable solvent. Thermosetting resin compositions
such as two-component polyurethane may be painted or sprayed over
the cylindrically braided reflective outer surface of the jewelry
piece. In Table A below there are listed a number of transparent
polymer compositions suitable for the jewelry abrasion resistant
coating. Also listed are the refractive indexes for the compositions.
TABLE-US-00001 TABLE A Polymer Name Refractive Index aliphatic thermoplastic
polyurethanes 1.35 to 1.45 Dow Corning OE-4100 Silicone elastomer
1.4751 Polymethyl tetradecyl siloxane 1.4550 Poly vinyl acetate
1.4665 PMMA Poly methyl methacrylate 1.4893 Cellulose acetate 1.4750
Ethylene/vinyl acetate copolymer EVA 1.4820
[0066] Thermoplastic aliphatic thermoplastic polyurethanes are
preferred as compared to aromatic urethanes because of their transparency,
resistance to dirt build-up, flexiblility ultraviolet radiation
degradation resistance. Typically, aliphatic polyurethane has the
structure
[0067] [--O--(CH(CH.sub.3)CH2O.sub.20--C(O)--NH--R--NH--C(O)--];
or
[0068] [--O--(CH.sub.2--CH.sub.2CH.sub.2 CH.sub.2--O--).sub.10--C(O)--NH--R--NH--C(O)--],
where R is a non-aromatic group.
[0069] Rohm and Haas, (Morton International Inc) supplies melt
extrudable polyurethane compositions under the trade name designation
MORTHANE L430.77 and MORTHANE Brand PN 3429-215. A melt extrusion
process may be used to coat the external surface of the cylindrically
braided reflective sleeve
[0070] Aptec Laboratories, 28570, Livingston Avenue, Valencia Calif.
91355-4171. 661-257-1677 markets polyurethane with low elastic modulus
for conformal coatings. Two component APTEK transparent unfilled
polyurethane compositions of interest include the composition 2503-A/B
(www.apteklabs.com/products/2503-AB.pdf) and the composition 2506-A/B
(www.apteklabs.com/products/2506.pdf). These two compositions are
designed for the encapsulation and protection of devices in applications
that require toughness, excellent flexibility and optimum tensile
strength, as well as elongation characteristics. APTEK 2503-A/B
is curable at 80 C while APTEK 2506-A/B is room temperature curable.
Both compositions are dissolved in a solvent and are therefore suitable
for brush or spray application.
[0071] Bayer provides a number of clear polyurethane coating compositions
based on one component or two component systems. Desmodular I aliphatic
diisocyanate is often abbreviated to IPDI, CAS 4098-71-9. Polyurethane
prepared from IPDI is clear, tough and resists photodegradation
and hydrolysis. Isocyanurate based on IPDI is marketed by Bayer
under the trade name Z-4470; and is available in a number of solvent
blends. Two component polyurethane is commonly formulated with Desmodur
Z-4470. Desmodur E polyisocyanates is a single component moisture
curable system capable of being diluted in a solvent.
[0072] www.setcochemicals.net/resins4.htm. supplies flexible room
temperature curing polyurethane coatings ROTOTHANE.RTM. 9020. This
coating adheres to plastics and leather.
[0073] Dow Corning supplies a number of silicone compositions suitable
for coating the cylindrically braided reflective strips to provide
abrasion resistance. Conformal coatings are materials applied in
thin layers (typically a few mils or a fraction of a mm) onto printed
circuits or other electronic substrates. They provide environmental
and mechanical protection to significantly extend the life of the
components and circuitry. Conformal coatings are traditionally applied
by dipping, spraying or simple flow coating, and increasingly by
select coating or robotic dispensing. Key requirements for the clear
coating are low viscosity, enabling application of thin conformal
coatings, room temperature cure in reasonable cure time and reasonable
hardness. In Table B below there are shown some of the conformal
silicone coatings marketed by Dow Corning. TABLE-US-00002 TABLE
B Product One part/ Viscosity Name Two part CPS Cure Durometer 3-1965
1 110 RT 24 Hrs 29 A Moisture cure 3-1953 1 360 RT 24 Hrs 26 A Moisture
Cure 3-1765 1 150 RT 24 Hrs 25 A Moisture cure 3-1753 1 385 RT 24
Hrs 25 A Moisture cure Sylgard 2 450 20 min/85 C. 64 OO 1-4128 I-4105
1 470 10 min/105 C. 65 OO QI-4010 1 830 15 min/110 C. 30 A I-2620
1 250 RT 72 Hrs 25 D Abrasion Resistant I-2577 1 1250 RT 72 Hrs
25 D LOW VOC Abrasion Resistant I-2577 1 725 RT 72 Hrs 23 D Abrasion
Resistant
[0074] Candidates for silicone conformal coating compositions that
meet the low viscosity in the range of 100-250 CPS, room temperature
cure in reasonable time period and reasonable hardness are coating
compositions 3-1965., 3-1765 and I-2620. These compositions may
be dipped, brush painted or sprayed.
[0075] Of particular interest is a Dow Corning OE-4100 optical
silicone elastomer, which cures in 2 hour at 150 C with a platinum
based catalyst, as discussed in www.dowcorning.com/content/photonic/75-1009B-01.pdf.
This composition is specifically developed for use in the optical
coating of optical components and is clear, transparent with a refractive
index of 1.47.
[0076] Polyvinyl acetate is soluble in acetone as well as toluene.
Acetone dissolved polyvinyl acetate film has a slightly higher elastic
modulus as compared to that dissolved in toluene due to rapid evaporation
of acetone. Acetone dissolved polyvinyl acetate is applied to the
cylindrically braided surface of the jewelry to form a flexible
film which is resistant to twisting action of a jewelry. Polyvinyl
acetate is available from Union Carbide under the trade names AYAC,
AYAA, AYAF and AYAT depending upon the molecular weight of the polymer.
[0077] FIG. 1a is a photograph of the jewelry piece, shown generally
at 10, having a male connector 13 located on the distal end, a female
connector 11 located on the proximal end, and a central jewelry
piece section 12. A cylindrically braided sleeve, created from braided
narrow width reflective strips, covers the central jewelry piece
section 12, providing substantially the entire surface of the jewelry
piece with omnidirectional reflectivity. The jewelry piece completely
reflects incident light in the same direction the light was emanated.
Due to the cylindrical character of the reflective braided sleeve,
some portion of the sleeve is always at normal orientation to the
incoming light beam, that is, the direction at which the reflection
from the retroreflective elements is maximized. Retroreflective
elements reflect light over a large range of acceptance angles,
but the reflection is at a lower intensity. This cylindrical construction
effectively reflects the incoming camera flash light as shown in
the photograph of FIG. 1a by the extremely bright appearance of
the retroreflectors 16 (see also FIG. 2) of the jewelry.
[0078] FIG. 1b shows a photograph of another view of the omnidirectional
reflective jewelry piece without using a camera flash. The illumination
comes from the room's light. The light here, again, is reflected
back to the illuminating source, and practically no light is directed
in the direction of the camera. As a result, the retroreflector
bright areas of FIG. 1a now appear dark.
[0079] The reflective jewelry piece's male connector 13 is composed
of a metallic material and the female connector 11 is comprised
of a magnetic portion adapted to magnetically engage with the male
connector. Alternatively, the male connector 13 is comprised a magnetic
member and the female connector 11 is composed of a metallic material
so that the male and female connectors, 13 and 11, respectively,
magnetically engage with one another. The male connector 13 may
comprise a magnetic member and the female connector 11 may comprise
a magnetic portion so that the male and female, 13 and 11, respectively,
magnetically engage with one another. In another embodiment, the
male connector 13 comprises a ribbed portion and the female connector
11 comprises a grooved aperture adapted to receive the ribbed portion
of the male connector 13. Alternatively, the male connector 13 and
the female connector 11 comprise a connection means, wherein the
connection means is selected from the group consisting of a Velcro,
hook and eye closure, snap closure, hook closure, or clasp closure.
[0080] FIG. 2 is a photograph of a magnified portion of the central
jewelry section 12. The photograph shows a transparent abrasion
resistant polymeric conformal coating substantially covering the
reflective cylindrical braided sleeve of narrow width strips surrounding
a central core. The cylindrical reflective braided sleeve is braided
with a small braid angle of 5 to 10 degrees between the narrow width
strips surrounding the central cylindrical rope core of the jewelry.
The central cylindrical rope core is completely covered by the cylindrical
reflective braided sleeve and therefore is invisible in the photograph.
The flexible nylon retroreflective sheet is shown at 16 and the
narrow width strip is shown at 15. The flexible nylon retroreflective
sheet 16 is thermally bonded to the narrow width strip 15 prior
to cylindrical braiding operation. The outer surface of the flexible
nylon retroreflective sheet 16 and the narrow width strip is covered
with a transparent conformal flexible abrasion resistant coating
14. The formation of the narrow width reflective strips is generally
shown at 20. A flexible retroreflective sheet 21 is thermally bonded
onto a nylon mesh strip 22 to form a flexible nylon retroreflective
sheet 16. The nylon mesh strip 22 is folded at phantom lines a.sub.1
in the direction indicated by arrows. The flexible nylon retroreflective
sheet 16, comprising flexible retroreflective sheet 21 thermally
bonded onto nylon mesh strip 22, is then sown onto a show surface
of a narrow width strip 15 at or near a.sub.1 to form a narrow width
reflective strip 25. At least three of these narrow width reflective
strips 25 are braided at a shallow cylindrical braid angle to form
an omnidirectionally reflective sleeve having a braided construction
that surrounds a central rope core, providing substantially the
entire surface of the jewelry with omnidirectional reflectivity.
[0081] FIG. 3 shows the female connector 11 located on the proximal
end of the reflective jewelry piece as attached to the reflective
cylindrical braided sleeve of narrow width strips. The female connector
11 is fixedly attached to the proximal end of the jewelry piece.
The central cylindrical braided rope core is completely covered
by the cylindrical reflective braided sleeve and the ends of the
braid are terminated by bonding to each strip at 17.
[0082] The key features of the abrasion resistant omnidirectionally
reflective jewelry includes, in combination, the features set forth
below: [0083] 1. a jewelry piece comprised of a central cylindrical
braided rope core composed of braided nylon or polypropylene fibers
capable of sustaining tensile forces; [0084] 2. the central cylindrical
braided rope core being covered substantially with a transparent
abrasion resistant conformal coating applied to a cylindrically
reflective braided sleeve; [0085] 3. the cylindrically reflective
braided sleeve formed by cylindrically braiding narrow width reflected
strips, formed from knitted, woven or braided nylon, or polypropylene
narrow width strips, having a flexible nylon retroreflective sheet,
comprising a flexible retroreflective sheet thermally bonded onto
a nylon mesh strip, sown to the surface thereof; [0086] 4. each
of the flexible retroreflector sheets being prepared by bonding
corner cube geometry retroreflectors to a flexible polymeric sheet
using a transparent binder; [0087] 5. such flexible retroreflector
sheets alternately being prepared by bonding microsphere geometry
retroreflectors to a metallized reflective flexible polymeric sheet
using a transparent binder; [0088] 6. each of the flexible retroreflective
sheets being thermally bonded to a nylon mesh strip to form a flexible
nylon retroreflective sheet; [0089] 7. twist and flexure forces
acting on the abrasion resistant omnidirectionally reflective jewelry
being accommodated by the braided construction of the cylindrical
reflective sleeve and the flexibility of abrasion resistant coating;
[0090] 8. the cylindrical braided sleeve-covered jewelry substantially
reflecting incident light back in the same direction as the incident
light, clearly indicating the whereabouts of the person wearing
the jewelry; and [0091] 9. the abrasion resistant omnidirectionally
reflective jewelry providing an increased margin of safety for wearers
while walking, hiking, jogging, bicycling, swimming, boating or
engaging in sport activities, or the like, in dimly lit environments,
such as parking garages, or inclement weather conditions, or on
water bodies such as lakes, inland waterways, rivers, harbors, canals
and the like, where rapidly moving vehicles or vessels are encountered.
[0092] The abrasion resistant omnidirectionally reflective jewelry
piece disclosed herein can be modified in numerous ways without
departing from the scope of the invention. For example, at least
one strip of the central braded rope core can be composed of leather.
The necklace, bracelet or anklet can be integral with the central
rope core or detachable therefrom via fastening means in the conventional
way. These and other modifications are intended to fall within the
scope of the invention, as defined by the subjoined claims.
[0093] Having thus described the invention in rather full detail,
it will be understood that such detail need not be strictly adhered
to, but that additional changes and modifications may suggest themselves
to one skilled in the art, all falling within the scope of the invention
as defined by the subjoined claims. |